Several other Reds are involved in friendlies with their respective countries, including Marouane Fellaini and Shinji Kagawa, who could face each other when Belgium meet Japan in Brussels.
"I'm looking forward to having a team-mate as an opponent," Kagawa said recently. "But it's not a one-on-one match-up - I hope we win as a team."
Wayne Rooney, Chris Smalling and Tom Cleverley have all been named in England’s side to take on Germany at Wembley, while Antonio Valencia’s Ecuador play Honduras in Houston.
Michael Keane, Wilfried Zaha, Jesse Lingard and Nick Powell are in the England Under-21s squad for their Euro 2015 qualifier against San Marino.
England's youngsters are currently three points clear with a game in hand at the top of their group in the 2015 U21 European Championship qualifiers and could extend that lead further at Shrewsbury Town's Greenhous Meadow Stadium.
Tues 19 Nov, 20:00 GMT unless stated
World Cup play-offs
Patrice Evra: FRANCE v Ukraine (0-2)
Nani: Sweden v PORTUGAL (0-1), 19:45
Wayne Rooney, Chris Smalling, Tom Cleverley: ENGLAND v Germany
Marouane Fellaini, Shinji Kagawa: BELGIUM v JAPAN
Antonio Valencia: Honduras v ECUADOR, 02:00 on 20 Nov
Under-21s Euro 2015 qualifying
Michael Keane, Wilfried Zaha, Jesse Lingard, Nick Powell: ENGLAND U21s v San Marino, 18:00